2013년 6월 27일 목요일

물리화학 9판 솔루션 (Atkins Physical Chemistry 9th Edition, P.W. Atkins(OXFORD))

물리화학 9판 솔루션 (Atkins Physical Chemistry 9th Edition, P.W. Atkins(OXFORD))
Physical Chemistry 9e Solutions Manual.pdf


목차
PART1. Equilibrium

PART2. Structure

PART3. Change

본문
D15.2
See Figures 15.8 and 15.10, the Brief Illustration in Section 15.3(a), and Self-test 15.6 for details. If the levels are non-degenerate, then both quantities increase from zero to a limiting value in a roughly sigmoidal shape. At very low temperatures, only the lower energy level is accessible, resulting in a highly ordered system at the energy of the lower level. At very high temperatures, the states are occupied practically equally, giving a highly disordered system whose mean energy is halfway between the two levels.

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